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1 article(s) from Sansalone, Lorenzo

Chemical tuning of photoswitchable azobenzenes: a photopharmacological case study using nicotinic transmission

Lorenzo Sansalone,
Jun Zhao,
Matthew T. Richers and
Graham C. R. Ellis-Davies

Beilstein J. Org. Chem. 2019, 15, 2812–2821, doi:10.3762/bjoc.15.274

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Figure 1: Fluoro-AB derivatives and spectra. Structures of 4FAB-diamides [13] cis and trans configurations, and t...

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Scheme 1: Synthesis of 4FABTA. a) Reagents and conditions: (a) 3-Butynol, PdCl₂(PPh₃)₂, CuI, THF, rt, 93%; (b...

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Figure 2: Photochemistry of 4FABTA (2), and thermodynamic stability in physiological buffer. a) Trans–cis pho...

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Figure 3: Reaction of t-4FABTA (1) with thiols, and thermal stability of initial conjugate. a) Chemical react...

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Figure 4: Testing photo-antagonism of 1 with genetically tagged nicotinic acetylcholine receptors. Currents f...

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Figure 5: Photopharmacology with 4FABTA (2). Currents from neurons in the medial habenula in acutely isolated...

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Published 21 Nov 2019

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